Nitrous oxide (N2O) is a greenhouse gas and an ozone-depleting agent with large and growing anthropogenic emissions. Previous studies identified the influx of N2O-depleted air from the stratosphere to partly cause the seasonality in tropospheric N2O (aN2O), but other contributions remain unclear. Here we combine surface fluxes from eight land and four ocean models from phase 2 of the Nitrogen/N2O Model Intercomparison Project with tropospheric transport modeling to simulate aN2O at the air sampling sites: Alert, Barrow, Ragged Point, Samoa, Ascension Island, and Cape Grim for the modern and preindustrial periods. Models show general agreement on the seasonal phasing of zonal-average N2O fluxes for most sites, but, seasonal peak-to-peak amplitudes differ severalfold across models. After transport, the seasonal amplitude of surface aN2O ranges from 0.25 to 0.80 ppb (interquartile ranges 21-52% of median) for land, 0.14 to 0.25 ppb (19-42%) for ocean, and 0.13 to 0.76 ppb (26-52%) for combined flux contributions. The observed range is 0.53 to 1.08 ppb. The stratospheric contributions to aN2O, inferred by the difference between surface-troposphere model and observations, show 36-126% larger amplitudes and minima delayed by ~1 month compared to Northern Hemisphere site observations. Our results demonstrate an increasing importance of land fluxes for aN2O seasonality, with land fluxes and their seasonal amplitude increasing since the preindustrial era and are projected to grow under anthropogenic activities. In situ aN2O observations and atmospheric transport-chemistry models will provide opportunities for constraining terrestrial and oceanic biosphere models, critical for projecting surface N2O sources under ongoing global warming.

The coastal ocean contributes to regulating atmospheric greenhouse gas concentrations by taking up carbon dioxide (CO2) and releasing nitrous oxide (N2O) and methane (CH4). Major advances have improved our understanding of the coastal air-sea exchanges of these three gasses since the first phase of the Regional Carbon Cycle Assessment and Processes (RECCAP in 2013), but a comprehensive view that integrates the three gasses at the global scale is still lacking. In this second phase (RECCAP2), we quantify global coastal ocean fluxes of CO2, N2O and CH4 using an ensemble of global gap-filled observation-based products and ocean biogeochemical models. The global coastal ocean is a net sink of CO2 in both observational products and models, but the magnitude of the median net global coastal uptake is ~60% larger in models (-0.72 vs. -0.44 PgC/yr, 1998-2018, coastal ocean area of 77 million km2). We attribute most of this model-product difference to the seasonality in sea surface CO2 partial pressure at mid- and high-latitudes, where models simulate stronger winter CO2 uptake. The global coastal ocean is a major source of N2O (+0.70 PgCO2-e /yr in observational product and +0.54 PgCO2-e /yr in model median) and of CH4 (+0.21 PgCO2-e /yr in observational product), which offsets a substantial proportion of the net radiative effect of coastal \co uptake (35-58% in CO2-equivalents). Data products and models need improvement to better resolve the spatio-temporal variability and long term trends in CO2, N2O and CH4 in the global coastal ocean.

Observations suggest that the tropical Pacific Ocean has lost oxygen since the 1960s leading to the expansion of its oxygen minimum zone (OMZ). Attribution to anthropogenic forcing is, however, difficult because of limited data availability and the large natural variability introduced by the Pacific Decadal Oscillation (PDO). Here, we evaluate the PDO influence on oxygen dynamics and OMZ extent using observations and hindcast simulations from two global ocean circulation models (NEMO-PISCES, MOM6-COBALT). In both models, the tropical Pacific oxygen content decreases by about 30 Tmol.decade$^{-1}$ and the OMZ volume expands by $1.3\times10^5$ km$^3$.decade$^{-1}$ during PDO positive phases, while variations of similar magnitude but opposite sign are simulated during negative phases. Changes in equatorial advective oxygen supply, partially offset by biological demand, control the oxygen response to PDO. Observations which cover 39\% of the tropical Pacific volume only partially capture spatio-temporal variability, hindering the separation of anthropogenic trend from natural variations.

The geographic rearrangement of the tropical oceanic and atmospheric circulation during an El Niño event is associated with a well-understood strong surface warming of the climatologically cold eastern equatorial Pacific. However, the concomitant warming of the warmest waters where deep convection occurs - responsible for the tropics-wide free tropospheric warming- is less well understood. Here, we show that in both a coupled atmosphere-ocean climate model and in reanalysis data, El Niño is associated with an increase in evaporation over the colder ~70%, but with a decrease in evaporation over the warmest ~30% of the tropical oceans where atmospheric deep convection connects the surface with the free troposphere. The reduction in evaporation is driven by a weakening of the near-surface winds. We propose that the prominent tropics-wide warming during El Niño is a consequence of the reduction of near-surface winds in regions of deep convection due to the anomalous large-scale circulation.

Global ocean oxygen loss - deoxygenation - is projected to persist in the future. Previous generations of Earth system models (ESMs) have, however, failed to provide a consistent picture of how deoxygenation will influence oxygen minimum zones (OMZs; O2<= 80 μmol/kg), in particular the largest OMZ in the tropical Pacific Ocean. The expansion of the Pacific OMZ would threaten marine ecosystems and ecosystem services such as fisheries and could amplify climate change by emitting greenhouse gases. Here, we use the latest generation of ESMs (CMIP6) and a density framework that isolates oxygen changes in the thermocline and intermediate waters. We show that the Pacific OMZ expands by the end of the century in response to high anthropogenic emissions (multi-ESM median expansion of 2.4 * 10^15 m^3m, about 4% of the observed OMZ volume). The expansion is driven by a reduction of the shallow overturning circulation in the thermocline and a robust weakening of the oxygen supply to the upper OMZ in all ESMs. The magnitude of this expansion is, however, uncertain due to the less constrained balance between physical and biological changes in the lower OMZ. Despite uncertainties in the biological response, our results suggest that models with more complex biogeochemistry project weaker changes in the lower OMZ, and therefore stronger overall OMZ expansion. The fact that the OMZ largely expands in the upper ocean maximizes its ecological, economic, and climatic impacts (release of greenhouse gases).