A document by Dale J. Allen. Click on the document to view its contents.

Manganese (Mn) is a key cofactor in enzymes responsible for lignin decay (mainly Mn peroxidase), regulating the rate of litter degradation and carbon (C) turnover in temperate and boreal forest biomes.While soil Mn is mainly derived from bedrock, atmospheric Mn could also contribute to soil Mn cycling, especially within the surficial horizon, with implications for soil C cycling. However, quantification of the atmospheric Mn cycle, which comprises emissions from natural (desert dust, sea salts, volcanoes, primary biogenic particles, and wildfires) and anthropogenic sources (e.g. industrialization and land-use change due to agriculture) transport, and deposition into the terrestrial and marine ecosystem, remains uncertain. Here, we use compiled emission datasets for each identified source to model and quantify the atmospheric Mn cycle with observational constraints. We estimated global emissions of atmospheric Mn in aerosols (<10 µm in aerodynamic diameter) to be 1500 Gg Mn yr-1. Approximately 32% of the emissions come from anthropogenic sources. Deposition of the anthropogenic Mn shortened soil Mn “pseudo” turnover times in surficial soils about 1-m depth (ranging from 1,000 to over 10,000,000 years) by 1-2 orders of magnitude in industrialized regions. Such anthropogenic Mn inputs boosted the Mn-to-N ratio of the atmospheric deposition in non-desert dominated regions (between 5×10-5 and 0.02) across industrialized areas, but still lower than soil Mn-to-N ratio by 1-3 orders of magnitude. Correlation analysis revealed a negative relationship between Mn deposition and topsoil C density across temperate and (sub)tropical forests, illuminating the role of Mn deposition in these ecosystems.

There is a need to better characterize aerosol absorption due to its remarkable radiative effects on climate. In particular, we need to understand the separation of total absorption between the two main components, the black carbon (BC) and brown carbon (BrC), especially in places where the anthropic influence is little, such as in pristine regions like Central Amazonia. The mechanisms that control the formation and evolution of BC and BrC in tropical forests remain unclear. In this study, we have performed detailed measurements at the Amazon Tall Tower Observatory (ATTO) tower on aerosols collected in Nuclepore filters and analyzed them with high-resolution optical spectrometers with a wide spectral range (300 to 2500 nm). Thus, we determined the absorption characteristics of BrC as a function of wavelength. The results show that BrC absorption is spectrally significant below 660 nm and is maximum at wavelengths close to 370 nm. Combining the measured spectral dependency with MIE modeling of the BC contribution, we determined that the BrC accounts for 14.8% of the total absorption. A similar fraction of BrC to total absorption was obtained through a similar analysis of in-situ measurements. Elemental chemical analysis of the filters, cluster, and factor analysis shows that the BrC is associated with airborne dust. The different methods to quantify BC and BrC are consistent and show similar results. This study will allow the quantification of the role of BrC and BC in aerosol absorption of radiation in Amazonia.