Corresponding Author
* Jiayi Liu, E-mail: 827487598@qq.com and *Wenhui Liu, E-mail: wenhuiliuzb@163.com
Funding: None
Conflict of interest statement: The authors declared that they have no conflicts of interest to this work. We declare that we do not have any commercial or associative interest that represents a conflict of interest in connection with the work submitted.
Permission to reproduce materials from other sources: None
Data Availability statement: The data used to support the findings of this study are available from the corresponding author upon request.
Abstract: In this study, a ZnCo2O4/Ag3PO4composite catalyst was prepared by the precipitation method, and its photocatalytic degradation activity for methyl orange (MO) was studied. The catalysts were characterized by TEM, XRD, EDX, HRTEM, SAED, SEM, XPS, and UV-Vis-DRS. The results indicate that 0.1 ZnCo2O4/Ag3PO4The composite system has a good photocatalytic degradation effect on methyl orange. Under 30-minute simulated sunlight conditions, the degradation rate can reach 94%. The results show that the maximum reaction rate constant of 0.1 ZnCo2O4/Ag3PO4is 0.05301 min-1, which is three times the size of pure Ag3PO4 and 52 times the size of pure ZnCo2O4. After three cycles, 0.1 ZnCo2O4/Ag3PO4still degraded methyl orange (MO) at a rate of 84.4%. The trapping experiment showed that hole (h+) and O2- played the most important roles in the photocatalytic degradation field of methyl orange (MO) by 0.1 ZnCo2O4/Ag3PO4, and hydroxyl radical (OH·) played a partial role. The energy level structure of ZnCo2O4/Ag3PO4is conducive to the effective separation of photogenerated electrons and holes, improving the lifespan of photogenerated charges. Among them, the photocatalytic performance of 0.1 ZnCo2O4/Ag3PO4is the most excellent.
Keywords: methyl orange; photocatalytic activity; photogenerated carriers