[a] Conditions: 1a (0.2 mmol), (R)-SKP (0.0021
mmol), [Rh(cod)2]SbF6 (0.002 mmol),
H2 (50 atm), DCM (2 mL), rt, 12 h, unless otherwise
noted. [b] The conversions were calculated from
1H-NMR spectra. [c] The ee values were determined
by HPLC using chiral columns. [d] H2 (30 atm). |
[a] Conditions: 1a (0.2 mmol), (R)-SKP (0.0021
mmol), [Rh(cod)2]SbF6 (0.002 mmol),
H2 (50 atm), DCM (2 mL), rt, 12 h, unless otherwise
noted. [b] The conversions were calculated from
1H-NMR spectra. [c] The ee values were determined
by HPLC using chiral columns. [d] H2 (30 atm). |
[a] Conditions: 1a (0.2 mmol), (R)-SKP (0.0021
mmol), [Rh(cod)2]SbF6 (0.002 mmol),
H2 (50 atm), DCM (2 mL), rt, 12 h, unless otherwise
noted. [b] The conversions were calculated from
1H-NMR spectra. [c] The ee values were determined
by HPLC using chiral columns. [d] H2 (30 atm). |
[a] Conditions: 1a (0.2 mmol), (R)-SKP (0.0021
mmol), [Rh(cod)2]SbF6 (0.002 mmol),
H2 (50 atm), DCM (2 mL), rt, 12 h, unless otherwise
noted. [b] The conversions were calculated from
1H-NMR spectra. [c] The ee values were determined
by HPLC using chiral columns. [d] H2 (30 atm). |
[a] Conditions: 1a (0.2 mmol), (R)-SKP (0.0021
mmol), [Rh(cod)2]SbF6 (0.002 mmol),
H2 (50 atm), DCM (2 mL), rt, 12 h, unless otherwise
noted. [b] The conversions were calculated from
1H-NMR spectra. [c] The ee values were determined
by HPLC using chiral columns. [d] H2 (30
atm). |