Table 2. Interfragment distances (R), magnitudes of the orientation factors |Θ|=|K|/2, magnitudes of unscreened (|V0|) and screened electronic couplings (|V|) and EET rates (k) between fragments of mTz-2I-BODIPY are shown. Table 2. Interfragment distances (R), magnitudes of the orientation factors |Θ|=|K|/2, magnitudes of unscreened (|V0|) and screened electronic couplings (|V|) and EET rates (k) between fragments of mTz-2I-BODIPY are shown. Table 2. Interfragment distances (R), magnitudes of the orientation factors |Θ|=|K|/2, magnitudes of unscreened (|V0|) and screened electronic couplings (|V|) and EET rates (k) between fragments of mTz-2I-BODIPY are shown. Table 2. Interfragment distances (R), magnitudes of the orientation factors |Θ|=|K|/2, magnitudes of unscreened (|V0|) and screened electronic couplings (|V|) and EET rates (k) between fragments of mTz-2I-BODIPY are shown. Table 2. Interfragment distances (R), magnitudes of the orientation factors |Θ|=|K|/2, magnitudes of unscreened (|V0|) and screened electronic couplings (|V|) and EET rates (k) between fragments of mTz-2I-BODIPY are shown. Table 2. Interfragment distances (R), magnitudes of the orientation factors |Θ|=|K|/2, magnitudes of unscreened (|V0|) and screened electronic couplings (|V|) and EET rates (k) between fragments of mTz-2I-BODIPY are shown.
Fragment Orientation
R, Å |Θ|, % |V0|, cm-1 |V|, cm-1 k, ps-1
Planar[Ref. 4] 6.83 48.97 106.60 59.44 1.31
Perpendicular[a] 6.95 0.06 5.81 3.24 3.90x10-3
[a]See Figure 3 [a]See Figure 3 [a]See Figure 3 [a]See Figure 3 [a]See Figure 3 [a]See Figure 3