Figure 2. The minimal building block library of
[P8W48O184]40−(abbreviated as {P8W48}) nodes and
transition metal linkers (Co, Mn, Ni, Ag) that forms a family of 14
POM-all inorganic framework architectures (namelly ”POMzites”). They all
share the {P8W48} building-block, with
simplified ring representation green and have the four structural
assembly types: chain (POMzite-4, 9,10, 14), column (POMzite-5, 6, 8,
11, 13), herringbone (POMzite-2, 7, 12) and cube (POMzite-3). We have
selected 10 representative examples of the 14 POMzite architectures. To
date, the explored experimental dataset consists of 30 POMzite
frameworks, but the accessible chemical space is vast.