Figure Captions
Figure. 1 XRD patterns of various calcined MWW zeolite samples.
Figure. 2 SEM images of (a) MCM-22 and (b)
MZN8-14.
Figure. 3 (a-c) TEM images of MZN8-14 with
different magnitude, (d) AFM topographic image of
MZN8-14
on a mica disc (inset, the profile analysis of the topographic height
along the line scan of the MWW nanosheet shown in (d)), (e-f) TEM images
of MCM-22 with different magnitude.
Figure. 4 (a) Conversion of 1-dodecene and (b) selectivity of
2-LAB with reaction time over various MWW zeolites.
Figure. 5 The binding energy of LAB isomers with 12- membered
ring pockets on the exterior surface of MWW layer and the corresponding
adsorption configuration.
Figure. 6 XRD patterns of calcined PMWW(31), PMWW(74) and
MCM-22 samples.
Figure. 7 SEM images of (a) PMWW(31) and (b) PMWW(74).
Figure. 8 TEM images of (a) PMWW(31) and (b) PMWW(74).
Figure. 9 (a) Conversion of 1-dodecene and (b) selectivity of
2-LAB with reaction time over PMWW(31) and PMWW(74), respectively.
Figure. 10 Al27 MAS NMR spectra of (a)
PMWW(31) and (b) PMWW(74) with the deconvolution and curve fitting.
Figure. 11 (a) Conversion of 1-dodecene and (b) selectivity of
2-LAB over MCM-22 and PMWW(74) with different cycles.
Figure. 12 XRD patterns of MCM-22 and PMWW(74) before and after
5 cycles.
Scheme 1 The proposed arrangements of pillared MWW lamellar at
(a) high and (b) low Si/Al ratios.