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Stable water isotopologue fractionation during soil-water evaporation: Analysis using a coupled soil-atmosphere model
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  • Stefanie Kiemle,
  • Katharina Heck,
  • Edward Coltman,
  • Rainer Helmig
Stefanie Kiemle
University of Stuttgart

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Katharina Heck
University of Stuttgart
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Edward Coltman
University of Stuttgart
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Rainer Helmig
University of Stuttgart
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Abstract

Stable water isotopologues tend to fractionate from ordinary water during evaporation processes resulting in an enrichment of the isotopic species in the soil. The fractionation process can be split into equilibrium fractionation and kinetic fractionation. Due to the complex coupled processes involved in simulating soil-water evaporation accurately, defining the kinetic fractionation correctly remains an open research area. In this work, we present a multi-phase multi-component transport model that resolves flow through both the near surface atmosphere and the soil, and models transport and fractionation of the stable water isotopologues using the numerical simulation environment DuMuX. Using this high resolution coupled model, we simulate transport and fractionation processes of stable water isotopologues in soils and the atmosphere without further parameterization of the kinetic fractionation process as is commonly done. In a series of examples, the transport and distribution of stable-water isotopologues are evaluated numerically with varied conditions and assumptions. First, an unsaturated porous medium connected to constant laminar flow conditions is introduced. The expected vertical isotope profiles in the soil as described in literature are reproduced. Further, by examining the spatial and temporal distribution of the isotopic composition, is determined the enrichment of the isotopologues in soil is linked with the different stages of the evaporation process. Building on these results, the robustness of the isotopic fractionation in our model is analysed by isolating single fractionation parameters. The effect of wind velocity and turbulent atmospheric conditions is investigated, leading to different kinetic fractionation scenarios and varied isotopic compositions in the soil.