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Particulate Oxalate-to-Sulfate Ratio as an Aqueous Processing Marker: Similarity Across Field Campaigns and Limitations
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  • Miguel Ricardo Hilario,
  • Ewan Crosbie,
  • Paola Angela Bañaga,
  • Grace Betito,
  • Rachel Anne Braun,
  • Maria Obiminda Cambaliza,
  • Andrea F Corral,
  • Melliza Templonuevo Cruz,
  • Jack E. Dibb,
  • Genevieve Rose Lorenzo,
  • Alexander Bruce MacDonald,
  • Claire E Robinson,
  • Michael Shook,
  • James Bernard Simpas,
  • Connor Stahl,
  • Edward L Winstead,
  • Luke D. Ziemba,
  • Armin Sorooshian
Miguel Ricardo Hilario
The University of Arizona,The University of Arizona, The University of Arizona
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Ewan Crosbie
Universities Space Research Association, Universities Space Research Association
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Paola Angela Bañaga
Manila Observatory, Manila Observatory
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Grace Betito
Manila Observatory, Manila Observatory
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Rachel Anne Braun
University of Arizona, University of Arizona
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Maria Obiminda Cambaliza
Manila Observatory, Manila Observatory
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Andrea F Corral
University of Arizona, University of Arizona
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Melliza Templonuevo Cruz
Manila Observatory, Manila Observatory
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Jack E. Dibb
University of New Hampshire, University of New Hampshire
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Genevieve Rose Lorenzo
Manila Observatory, Manila Observatory
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Alexander Bruce MacDonald
University of Arizona, University of Arizona
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Claire E Robinson
Science Systems and Applications, Science Systems and Applications
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Michael Shook
Langley Research Center, Langley Research Center
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James Bernard Simpas
Manila Observatory, Manila Observatory
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Connor Stahl
University of Arizona, University of Arizona
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Edward L Winstead
NASA Langley Research Center, NASA Langley Research Center
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Luke D. Ziemba
NASA Langley Research Center, NASA Langley Research Center
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Armin Sorooshian
University of Arizona, University of Arizona

Corresponding Author:[email protected]

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Abstract

Leveraging aerosol data from multiple airborne and surface-based field campaigns encompassing diverse environmental conditions, we calculate statistics of the oxalate-sulfate mass ratio (median: 0.0217; 95% confidence interval: 0.0154 – 0.0296; R = 0.76; N = 2948). Ground-based measurements of the oxalate-sulfate ratio fall within our 95% confidence interval, suggesting the range is robust within the mixed layer for the submicrometer particle size range. We demonstrate that dust and biomass burning emissions can separately bias this ratio towards higher values by at least one order of magnitude. In the absence of these confounding factors, the 95% confidence interval of the ratio may be used to estimate the relative extent of aqueous processing by comparing inferred oxalate concentrations between air masses, with the assumption that sulfate primarily originates from aqueous processing.
16 Dec 2021Published in Geophysical Research Letters volume 48 issue 23. 10.1029/2021GL096520